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Zhao CW, Ma JP, Liu QK, et al. An in situ self-assembled Cu4I4-MOF-based mixed matrix membrane: a highly sensitive and selective naked-eye sensor for gaseous HCl. Chem Commun (Camb). 2016;52(30):5238-41doi: 10.1039/c6cc00189k.
Zhao, C. W., Ma, J. P., Liu, Q. K., Wang, X. R., Liu, Y., Yang, J., Yang, J. S., & Dong, Y. B. (2016). An in situ self-assembled Cu4I4-MOF-based mixed matrix membrane: a highly sensitive and selective naked-eye sensor for gaseous HCl. Chemical communications (Cambridge, England), 52(30), 5238-41. https://doi.org/10.1039/c6cc00189k
Zhao, Chao-Wei, et al. "An in situ self-assembled Cu4I4-MOF-based mixed matrix membrane: a highly sensitive and selective naked-eye sensor for gaseous HCl." Chemical communications (Cambridge, England) vol. 52,30 (2016): 5238-41. doi: https://doi.org/10.1039/c6cc00189k
Zhao CW, Ma JP, Liu QK, Wang XR, Liu Y, Yang J, Yang JS, Dong YB. An in situ self-assembled Cu4I4-MOF-based mixed matrix membrane: a highly sensitive and selective naked-eye sensor for gaseous HCl. Chem Commun (Camb). 2016 Apr 18;52(30):5238-41. doi: 10.1039/c6cc00189k. Epub 2016 Feb 29. PMID: 26923526.
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Chem Commun (Camb). 2016 Apr 18;52(30):5238-41. doi: 10.1039/c6cc00189k. Epub 2016 Feb 29.

An in situ self-assembled Cu4I4-MOF-based mixed matrix membrane: a highly sensitive and selective naked-eye sensor for gaseous HCl.

Chemical communications (Cambridge, England)

Chao-Wei Zhao, Jian-Ping Ma, Qi-Kui Liu, Xue-Ru Wang, Yi Liu, Jing Yang, Jia-Shi Yang, Yu-Bin Dong

Affiliations

  1. College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China. [email protected].

PMID: 26923526 DOI: 10.1039/c6cc00189k

Abstract

The Cu4I4-MOF-based mixed matrix membranes (MMMs) can be readily prepared by one-step in situ self-assembly of a tri-armed oxadiazole-bridged ligand and CuI in polymer binder solution under ambient conditions. The visual and luminescent HCl(g) sensing detecting limits of the resulting Cu4I4-MOF-based MMMs are 3.2 and 1.6 ppb, respectively, and the response time is less than 1 min.

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