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Org Biomol Chem. 2016 Apr 26;14(17):4039-45. doi: 10.1039/c6ob00064a.

Fluorescent cross-linked supramolecular polymers constructed from a novel self-complementary AABB-type heteromultitopic monomer.

Organic & biomolecular chemistry

Le Fang, Yuanli Hu, Qiang Li, Shutao Xu, Manivannan Kalavathi Dhinakarank, Weitao Gong, Guiling Ning

Affiliations

  1. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China. [email protected].
  2. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physic, Chinese Academy of Sciences, Dalian 116023, P. R. China.
  3. National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China.

PMID: 27005489 DOI: 10.1039/c6ob00064a

Abstract

A novel AABB-type heteromultitopic monomer (), having a self-complementary perpendicular structure, could solely self-assemble to fluorescent cross-linked supramolecular polymers. Interestingly, the supramolecular gel film shows a sensitive fluorescence change on exposure to acid and base vapor, endowing this system with a potential application in gas detection.

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