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Jassal V, Shanker U, Kaith BS. Aegle marmelos Mediated Green Synthesis of Different Nanostructured Metal Hexacyanoferrates: Activity against Photodegradation of Harmful Organic Dyes. Scientifica (Cairo). 2016;2016:2715026doi: 10.1155/2016/2715026.
Jassal, V., Shanker, U., & Kaith, B. S. (2016). Aegle marmelos Mediated Green Synthesis of Different Nanostructured Metal Hexacyanoferrates: Activity against Photodegradation of Harmful Organic Dyes. Scientifica, 20162715026. https://doi.org/10.1155/2016/2715026
Jassal, Vidhisha, et al. "Aegle marmelos Mediated Green Synthesis of Different Nanostructured Metal Hexacyanoferrates: Activity against Photodegradation of Harmful Organic Dyes." Scientifica vol. 2016 (2016): 2715026. doi: https://doi.org/10.1155/2016/2715026
Jassal V, Shanker U, Kaith BS. Aegle marmelos Mediated Green Synthesis of Different Nanostructured Metal Hexacyanoferrates: Activity against Photodegradation of Harmful Organic Dyes. Scientifica (Cairo). 2016;2016:2715026. doi: 10.1155/2016/2715026. Epub 2016 Feb 29. PMID: 27034896; PMCID: PMC4789527.
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Scientifica (Cairo). 2016;2016:2715026. doi: 10.1155/2016/2715026. Epub 2016 Feb 29.

Aegle marmelos Mediated Green Synthesis of Different Nanostructured Metal Hexacyanoferrates: Activity against Photodegradation of Harmful Organic Dyes.

Scientifica

Vidhisha Jassal, Uma Shanker, B S Kaith

Affiliations

  1. Department of Chemistry, Dr. B. R. Ambedkar National Institute of Technology, Jalandhar, Punjab 144011, India.

PMID: 27034896 PMCID: PMC4789527 DOI: 10.1155/2016/2715026

Abstract

Prussian blue analogue potassium metal hexacyanoferrate (KMHCF) nanoparticles Fe4[Fe(CN)6]3 (FeHCF), K2Cu3[Fe(CN)6]2 (KCuHCF), K2Ni[Fe(CN)6]·3H2O (KNiHCF), and K2Co[Fe(CN)6] (KCoHCF) have been synthesized using plant based biosurfactant Aegle marmelos (Bael) and water as a green solvent. It must be emphasized here that no harmful reagent or solvent was used throughout the study. Plant extracts are easily biodegradable and therefore do not cause any harm to the environment. Hence, the proposed method of synthesis of various KMHCF nanoparticles followed a green path. The synthesized nanoparticles were characterized by powder X-ray diffraction (PXRD), Field-Emission Scanning Electron Microscopy (FE-SEM), Transmission Electron Microscopy (TEM), and Fourier Transform Infrared Spectroscopy (FT-IR). MHCF nanoparticles were used for the photocatalytic degradation of toxic dyes like Malachite Green (MG), Eriochrome Black T (EBT), Methyl Orange (MO), and Methylene Blue (MB). Under optimized reaction conditions, maximum photocatalytic degradation was achieved in case of KCuHCF nanoparticles mediated degradation process (MG: 96.06%, EBT: 83.03%, MB: 94.72%, and MO: 63.71%) followed by KNiHCF (MG: 95%, EBT: 80.32%, MB: 91.35%, and MO: 59.42%), KCoHCF (MG: 91.45%, EBT: 78.84%, MB: 89.28%, and MO: 58.20%).

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