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Noll J, Korb M, Lang H. Crystal structure of bis-[tetra-kis-(tri-phenyl-phosphane-κP)silver(I)] (nitrilo-tri-acetato-κ(4) N,O,O',O'')(tri-phenyl-phosphane-κP)argentate(I) with an unknown amount of methanol as solvate. Acta Crystallogr E Crystallogr Commun. 2016;72:318-21doi: 10.1107/S2056989016001262.
Noll, J., Korb, M., & Lang, H. (2016). Crystal structure of bis-[tetra-kis-(tri-phenyl-phosphane-κP)silver(I)] (nitrilo-tri-acetato-κ(4) N,O,O',O'')(tri-phenyl-phosphane-κP)argentate(I) with an unknown amount of methanol as solvate. Acta crystallographica. Section E, Crystallographic communications, 72318-21. https://doi.org/10.1107/S2056989016001262
Noll, Julian, et al. "Crystal structure of bis-[tetra-kis-(tri-phenyl-phosphane-κP)silver(I)] (nitrilo-tri-acetato-κ(4) N,O,O',O'')(tri-phenyl-phosphane-κP)argentate(I) with an unknown amount of methanol as solvate." Acta crystallographica. Section E, Crystallographic communications vol. 72 (2016): 318-21. doi: https://doi.org/10.1107/S2056989016001262
Noll J, Korb M, Lang H. Crystal structure of bis-[tetra-kis-(tri-phenyl-phosphane-κP)silver(I)] (nitrilo-tri-acetato-κ(4) N,O,O',O'')(tri-phenyl-phosphane-κP)argentate(I) with an unknown amount of methanol as solvate. Acta Crystallogr E Crystallogr Commun. 2016 Feb 10;72:318-21. doi: 10.1107/S2056989016001262. eCollection 2016 Mar 01. PMID: 27006796; PMCID: PMC4778820.
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Acta Crystallogr E Crystallogr Commun. 2016 Feb 10;72:318-21. doi: 10.1107/S2056989016001262. eCollection 2016 Mar 01.

Crystal structure of bis-[tetra-kis-(tri-phenyl-phosphane-κP)silver(I)] (nitrilo-tri-acetato-κ(4) N,O,O',O'')(tri-phenyl-phosphane-κP)argentate(I) with an unknown amount of methanol as solvate.

Acta crystallographica. Section E, Crystallographic communications

Julian Noll, Marcus Korb, Heinrich Lang

Affiliations

  1. Technische Universität Chemnitz, Fakultät für Naturwissenschaften, Institut für Chemie, Anorganische Chemie, D-09107 Chemnitz, Germany.

PMID: 27006796 PMCID: PMC4778820 DOI: 10.1107/S2056989016001262

Abstract

The structure of the title compound, [Ag(C18H15P)4]2[Ag(C6H6NO6)(C18H15P)], exhibits trigonal (P-3) symmetry, with a C 3 axis through all three complex ions, resulting in an asymmetric unit that contains one third of the atoms present in the formula unit. The formula unit thus contains two of the cations, one anion and disordered mol-ecules of methanol as the packing solvent. Attempts to refine the solvent model were unsuccessful, indicating uninter-pretable disorder. Thus, the SQUEEZE procedure in PLATON [Spek (2015 ▸). Acta Cryst. C71, 9-18] was applied, accounting for 670 electrons per unit cell, representing approximately 18 mol-ecules of methanol in the formula unit. The stated crystal data for M r, μ etc do not take these into account.

Keywords: SQUEEZE; crystal structure; non-coordinating anion; silver; triphenyl phosphine

References

  1. Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55 - PubMed
  2. Acta Crystallogr Sect E Struct Rep Online. 2014 Sep 10;70(Pt 10):174-7 - PubMed
  3. Chem Commun (Camb). 2013 May 11;49(38):3991-3 - PubMed
  4. Acta Crystallogr C Struct Chem. 2015 Jan;71(Pt 1):3-8 - PubMed
  5. Dalton Trans. 2013 Nov 28;42(44):15599-609 - PubMed
  6. J Colloid Interface Sci. 2013 Sep 15;406:256-62 - PubMed
  7. ACS Appl Mater Interfaces. 2015 Jun 17;7(23):12679-87 - PubMed
  8. Chem Soc Rev. 2006 Nov;35(11):1162-94 - PubMed
  9. Acta Crystallogr C Struct Chem. 2015 Jan;71(Pt 1):9-18 - PubMed
  10. Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22 - PubMed
  11. Acta Crystallogr Sect E Struct Rep Online. 2012 Dec 1;68(Pt 12):m1536 - PubMed

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