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Zuber J, Kroll MM, Rathsack P, et al. Gas Chromatography/Atmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal. Int J Anal Chem. 2016;2016:5960916doi: 10.1155/2016/5960916.
Zuber, J., Kroll, M. M., Rathsack, P., & Otto, M. (2016). Gas Chromatography/Atmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal. International journal of analytical chemistry, 20165960916. https://doi.org/10.1155/2016/5960916
Zuber, Jan, et al. "Gas Chromatography/Atmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal." International journal of analytical chemistry vol. 2016 (2016): 5960916. doi: https://doi.org/10.1155/2016/5960916
Zuber J, Kroll MM, Rathsack P, Otto M. Gas Chromatography/Atmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal. Int J Anal Chem. 2016;2016:5960916. doi: 10.1155/2016/5960916. Epub 2016 Mar 15. PMID: 27066076; PMCID: PMC4811094.
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Int J Anal Chem. 2016;2016:5960916. doi: 10.1155/2016/5960916. Epub 2016 Mar 15.

Gas Chromatography/Atmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal.

International journal of analytical chemistry

Jan Zuber, Marius M Kroll, Philipp Rathsack, Matthias Otto

Affiliations

  1. Institute of Analytical Chemistry, TU Bergakademie Freiberg, 09599 Freiberg, Germany.
  2. Institute of Analytical Chemistry, TU Bergakademie Freiberg, 09599 Freiberg, Germany; German Centre for Energy Resources, Reiche Zeche, Fuchsmuehlenweg 9, 09599 Freiberg, Germany.

PMID: 27066076 PMCID: PMC4811094 DOI: 10.1155/2016/5960916

Abstract

Pyrolysis oil from the slow pyrolysis of German brown coal from Schöningen, obtained at a temperature of 500°C, was separated and analyzed using hyphenation of gas chromatography with an atmospheric pressure chemical ionization source operated in negative ion mode and Fourier transform ion cyclotron resonance mass spectrometry (GC-APCI-FT-ICR-MS). Development of this ultrahigh-resolving analysis method is described, that is, optimization of specific GC and APCI parameters and performed data processing. The advantages of GC-APCI-FT-ICR-MS hyphenation, for example, soft ionization, ultrahigh-resolving detection, and most important isomer separation, were demonstrated for the sample liquid. For instance, it was possible to separate and identify nine different propylphenol, ethylmethylphenol, and trimethylphenol isomers. Furthermore, homologous series of different acids, for example, alkyl and alkylene carboxylic acids, were verified, as well as homologous series of alkyl phenols, alkyl dihydroxy benzenes, and alkoxy alkyl phenols.

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