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Rossin A, Peruzzini M. Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides. Chem Rev. 2016;116(15):8848-72doi: 10.1021/acs.chemrev.6b00043.
Rossin, A., & Peruzzini, M. (2016). Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides. Chemical reviews, 116(15), 8848-72. https://doi.org/10.1021/acs.chemrev.6b00043
Rossin, Andrea, and Peruzzini, Maurizio. "Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides." Chemical reviews vol. 116,15 (2016): 8848-72. doi: https://doi.org/10.1021/acs.chemrev.6b00043
Rossin A, Peruzzini M. Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides. Chem Rev. 2016 Aug 10;116(15):8848-72. doi: 10.1021/acs.chemrev.6b00043. Epub 2016 Apr 14. PMID: 27075435.
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Chem Rev. 2016 Aug 10;116(15):8848-72. doi: 10.1021/acs.chemrev.6b00043. Epub 2016 Apr 14.

Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides.

Chemical reviews

Andrea Rossin, Maurizio Peruzzini

Affiliations

  1. Institute of Chemistry of Organometallic Compounds, ICCOM-CNR , Via Madonna del Piano 10, 50019 Sesto Fiorentino (Florence), Italy.

PMID: 27075435 DOI: 10.1021/acs.chemrev.6b00043

Abstract

This review is a comprehensive survey of the last 10 years of research on ammonia-borane and amine-borane dehydrogenation mediated by complex metal hydrides (CMHs), within the broader context of chemical hydrogen storage. The review also collects those cases where CMHs are the catalyst spent form or its resting state. Highlights on the reaction mechanism (strictly dependent on the CMH of choice) and the catalysts efficiency (in terms of equivalents of H2 produced and relative reaction rates) are provided throughout the discussion.

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