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Chem Commun (Camb). 2016 Jun 04;52(44):7161-3. doi: 10.1039/c6cc03096c. Epub 2016 May 12.

A Pt/Al2O3-supported metal-organic framework film as the size-selective core-shell hydrogenation catalyst.

Chemical communications (Cambridge, England)

Sonia Aguado, Sawsan El-Jamal, Frederic Meunier, Jerome Canivet, David Farrusseng

Affiliations

  1. IRCELYON, UMR CNRS 5256 - Université Lyon 1, 2 av. Albert Einstein, 69626 Villeurbanne Cedex, France. [email protected].

PMID: 27172134 DOI: 10.1039/c6cc03096c

Abstract

The substituted imidazolate-based MOF (SIM-1) easily forms a homogeneous layer at the surface of millimetric platinum-loaded alumina beads. This new core-shell SIM-1@Pt/Al2O3 catalyst shows the fine molecular sieving effect for the Pt-catalyzed hydrogenation of carbon-carbon double bonds.

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