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Ungarean CN, Southgate EH, Sarlah D. Enantioselective polyene cyclizations. Org Biomol Chem. 2016;14(24):5454-67doi: 10.1039/c6ob00375c.
Ungarean, C. N., Southgate, E. H., & Sarlah, D. (2016). Enantioselective polyene cyclizations. Organic & biomolecular chemistry, 14(24), 5454-67. https://doi.org/10.1039/c6ob00375c
Ungarean, Chad N, et al. "Enantioselective polyene cyclizations." Organic & biomolecular chemistry vol. 14,24 (2016): 5454-67. doi: https://doi.org/10.1039/c6ob00375c
Ungarean CN, Southgate EH, Sarlah D. Enantioselective polyene cyclizations. Org Biomol Chem. 2016 Jun 28;14(24):5454-67. doi: 10.1039/c6ob00375c. Epub 2016 May 04. PMID: 27143099.
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Org Biomol Chem. 2016 Jun 28;14(24):5454-67. doi: 10.1039/c6ob00375c. Epub 2016 May 04.

Enantioselective polyene cyclizations.

Organic & biomolecular chemistry

Chad N Ungarean, Emma H Southgate, David Sarlah

Affiliations

  1. Roger Adams Laboratory, Department of Chemistry, University of Illinois, Urbana, Illinois 61801, USA. [email protected].

PMID: 27143099 DOI: 10.1039/c6ob00375c

Abstract

The cyclization of polyolefins represents a powerful tool for the rapid generation of molecular complexity. Within the last decade, significant discoveries have been made in the development of methods for converting prochiral polyene substrates into the corresponding polycyclic products with high levels of enantiocontrol. This review highlights advances in the area of enantioselective polyene cyclizations and their use in the synthesis of complex secondary metabolites.

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