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Adv Mater. 2016 Sep;28(35):7564-79. doi: 10.1002/adma.201601357. Epub 2016 Jun 30.

An Overview and Future Perspectives of Aluminum Batteries.

Advanced materials (Deerfield Beach, Fla.)

Giuseppe Antonio Elia, Krystan Marquardt, Katrin Hoeppner, Sebastien Fantini, Rongying Lin, Etienne Knipping, Willi Peters, Jean-Francois Drillet, Stefano Passerini, Robert Hahn

Affiliations

  1. Technische Universität Berlin, Research Center of Microperipheric Technologies, Gustav-Meyer-Allee 25, 13355, Berlin, Germany. [email protected].
  2. Technische Universität Berlin, Research Center of Microperipheric Technologies, Gustav-Meyer-Allee 25, 13355, Berlin, Germany.
  3. Solvionic SA, Chemin de la Loge, CS 27813, 31078, Toulouse, France.
  4. LEITAT Technological Center, C/ de la Innovació, 2 08225, Terrassa, Barcelona, Spain.
  5. DECHEMA-Forschungsinstitut, Theodor-Heuss-Allee 25, 60486, Frankfurt am Main, Germany.
  6. Helmholtz Institute Ulm (HIU), Helmholtzstrasse 11, 89081, Ulm, Germany. [email protected].
  7. Karlsruhe Institute of Technology (KIT), P.O. Box 3640, 76021, Karlsruhe, Germany. [email protected].
  8. Fraunhofer IZM, Gustav-Meyer-Allee 25, 13355, Berlin, Germany. [email protected].

PMID: 27357902 DOI: 10.1002/adma.201601357

Abstract

A critical overview of the latest developments in the aluminum battery technologies is reported. The substitution of lithium with alternative metal anodes characterized by lower cost and higher abundance is nowadays one of the most widely explored paths to reduce the cost of electrochemical storage systems and enable long-term sustainability. Aluminum based secondary batteries could be a viable alternative to the present Li-ion technology because of their high volumetric capacity (8040 mAh cm(-3) for Al vs 2046 mAh cm(-3) for Li). Additionally, the low cost aluminum makes these batteries appealing for large-scale electrical energy storage. Here, we describe the evolution of the various aluminum systems, starting from those based on aqueous electrolytes to, in more details, those based on non-aqueous electrolytes. Particular attention has been dedicated to the latest development of electrolytic media characterized by low reactivity towards other cell components. The attention is then focused on electrode materials enabling the reversible aluminum intercalation-deintercalation process. Finally, we touch on the topic of high-capacity aluminum-sulfur batteries, attempting to forecast their chances to reach the status of practical energy storage systems.

© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: aluminum batteries; batteries; cathodes; electrolytes; energy storage

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