Display options
Cite
Pointillart F, Liu X, Kepenekian M, et al. Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand. Dalton Trans. 2016;45(28):11267-71doi: 10.1039/c6dt00920d.
Pointillart, F., Liu, X., Kepenekian, M., Le Guennic, B., Golhen, S., Dorcet, V., Roisnel, T., Cador, O., You, Z., Hauser, J., Decurtins, S., Ouahab, L., & Liu, S. X. (2016). Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand. Dalton transactions (Cambridge, England : 2003), 45(28), 11267-71. https://doi.org/10.1039/c6dt00920d
Pointillart, F, et al. "Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand." Dalton transactions (Cambridge, England : 2003) vol. 45,28 (2016): 11267-71. doi: https://doi.org/10.1039/c6dt00920d
Pointillart F, Liu X, Kepenekian M, Le Guennic B, Golhen S, Dorcet V, Roisnel T, Cador O, You Z, Hauser J, Decurtins S, Ouahab L, Liu SX. Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand. Dalton Trans. 2016 Jul 28;45(28):11267-71. doi: 10.1039/c6dt00920d. Epub 2016 Jun 30. PMID: 27358063.
Copy Download .nbib Format: NLM
Share it on

Dalton Trans. 2016 Jul 28;45(28):11267-71. doi: 10.1039/c6dt00920d. Epub 2016 Jun 30.

Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand.

Dalton transactions (Cambridge, England : 2003)

F Pointillart, X Liu, M Kepenekian, B Le Guennic, S Golhen, V Dorcet, T Roisnel, O Cador, Z You, J Hauser, S Decurtins, L Ouahab, S-X Liu

Affiliations

  1. Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS - Université de Rennes 1, 35042, Rennes Cedex, France. [email protected].

PMID: 27358063 DOI: 10.1039/c6dt00920d

Abstract

A mononuclear Fe(ii) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.

Publication Types