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Miyake N, Kurata T. Autoxidation Reaction Mechanism for L-Ascorbic Acid-related Compounds in Methanol without Metal Ion Catalysis. Biosci Biotechnol Biochem. 1998;62(4):811-3doi: 10.1271/bbb.62.811.
Miyake, N., & Kurata, T. (1998). Autoxidation Reaction Mechanism for L-Ascorbic Acid-related Compounds in Methanol without Metal Ion Catalysis. Bioscience, biotechnology, and biochemistry, 62(4), 811-3. https://doi.org/10.1271/bbb.62.811
Miyake, N, and Kurata, T. "Autoxidation Reaction Mechanism for L-Ascorbic Acid-related Compounds in Methanol without Metal Ion Catalysis." Bioscience, biotechnology, and biochemistry vol. 62,4 (1998): 811-3. doi: https://doi.org/10.1271/bbb.62.811
Miyake N, Kurata T. Autoxidation Reaction Mechanism for L-Ascorbic Acid-related Compounds in Methanol without Metal Ion Catalysis. Biosci Biotechnol Biochem. 1998;62(4):811-3. doi: 10.1271/bbb.62.811. PMID: 27392564.
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Biosci Biotechnol Biochem. 1998;62(4):811-3. doi: 10.1271/bbb.62.811.

Autoxidation Reaction Mechanism for L-Ascorbic Acid-related Compounds in Methanol without Metal Ion Catalysis.

Bioscience, biotechnology, and biochemistry

N Miyake, T Kurata

Affiliations

  1. a Institute of Environmental Science for Human Life, Ochanomizu University.

PMID: 27392564 DOI: 10.1271/bbb.62.811

Abstract

The autoxidation mechanism for L-ascorbic acid (ASA)-related compounds such as D-arabo-ascorbic acid (=erythorbic acid; ERA) and triose reductone (TR) in methanol without metal ion catalysis was studied. The oxidation reaction of these ASA-related compounds seems to proceed via the C(2) oxygen adduct of ERA (or TR) by a similar reaction mechanism to that of ASA.

Keywords: C(2) oxygen adduct; D-erythorbic acid; L-ascorbic acid; autoxidation; triose reductone

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