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ACS Appl Mater Interfaces. 2016 Jul 13;8(27):17668-75. doi: 10.1021/acsami.6b04192. Epub 2016 Jun 30.

Deformation Hysteresis of Electrohydrodynamic Patterning on a Thin Polymer Film.

ACS applied materials & interfaces

Qingzhen Yang, Ben Q Li, Hongmiao Tian, Xiangming Li, Jinyou Shao, Xiaoliang Chen, Feng Xu

Affiliations

  1. Department of Mechanical Engineering, University of Michigan-Dearborn , Dearborn, Michigan 48128, United States.

PMID: 27326791 DOI: 10.1021/acsami.6b04192

Abstract

Electrohydrodynamic patterning is a technique that enables micro/nanostructures via imposing an external voltage on thin polymer films. In this investigation, we studied the electrohydrodynamic patterning theoretically and experimentally, with special interest focused on the equilibrium state. It is found that the equilibrium structure height increases with the voltage. In addition, we have observed, and believe it to be the first time, a hysteresis phenomenon exists in the relationship between the voltage and structure height. With an increase in the voltage, a critical value (the first critical voltage) is noticed, above which the polymer film would increase dramatically until it comes into contact with the template. However, with a decrease in the voltage, a smaller voltage (the second critical voltage) is needed to detach the polymer from the template. The mismatch of the first and second critical voltages distorts the voltage-structure height curve into an "S" shape. Such a phenomenon is verified for three representative templates and also by experiments. Furthermore, the effects of some parameters (e.g., polymer film thickness and dielectric constant) on this hysteresis phenomenon are also discussed.

Keywords: electrohydrodynamics; hysteresis phenomenon; micro/nanopatterning; numerical modeling; polymer film

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