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Schenk AK, Rietwyk KJ, Tadich A, et al. High resolution core level spectroscopy of hydrogen-terminated (1 0 0) diamond. J Phys Condens Matter. 2016;28(30):305001doi: 10.1088/0953-8984/28/30/305001.
Schenk, A. K., Rietwyk, K. J., Tadich, A., Stacey, A., Ley, L., & Pakes, C. I. (2016). High resolution core level spectroscopy of hydrogen-terminated (1 0 0) diamond. Journal of physics. Condensed matter : an Institute of Physics journal, 28(30), 305001. https://doi.org/10.1088/0953-8984/28/30/305001
Schenk, A K, et al. "High resolution core level spectroscopy of hydrogen-terminated (1 0 0) diamond." Journal of physics. Condensed matter : an Institute of Physics journal vol. 28,30 (2016): 305001. doi: https://doi.org/10.1088/0953-8984/28/30/305001
Schenk AK, Rietwyk KJ, Tadich A, Stacey A, Ley L, Pakes CI. High resolution core level spectroscopy of hydrogen-terminated (1 0 0) diamond. J Phys Condens Matter. 2016 Aug 03;28(30):305001. doi: 10.1088/0953-8984/28/30/305001. Epub 2016 Jun 14. PMID: 27299369.
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J Phys Condens Matter. 2016 Aug 03;28(30):305001. doi: 10.1088/0953-8984/28/30/305001. Epub 2016 Jun 14.

High resolution core level spectroscopy of hydrogen-terminated (1 0 0) diamond.

Journal of physics. Condensed matter : an Institute of Physics journal

A K Schenk, K J Rietwyk, A Tadich, A Stacey, L Ley, C I Pakes

Affiliations

  1. Department of Chemistry and Physics, La Trobe Institute for Molecular Sciences, La Trobe University, Victoria 3086, Australia.

PMID: 27299369 DOI: 10.1088/0953-8984/28/30/305001

Abstract

Synchrotron-based photoelectron spectroscopy experiments are presented that address a long standing inconsistency in the treatment of the C1s core level of hydrogen terminated (1 0 0) diamond. Through a comparison of surface and bulk sensitive measurements we show that there is a surface related core level component to lower binding energy of the bulk diamond component; this component has a chemical shift of [Formula: see text] eV which has been attributed to carbon atoms which are part of the hydrogen termination. Additionally, our results indicate that the asymmetry of the hydrogen terminated (1 0 0) diamond C1s core level is an intrinsic aspect of the bulk diamond peak which we have attributed to sub-surface carbon layers.

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