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Science. 2016 Jun 17;352(6292):1449-52. doi: 10.1126/science.aae0328. Epub 2016 Jun 14.

Discovery of the interstellar chiral molecule propylene oxide (CH₃CHCH₂O).

Science (New York, N.Y.)

Brett A McGuire, P Brandon Carroll, Ryan A Loomis, Ian A Finneran, Philip R Jewell, Anthony J Remijan, Geoffrey A Blake

Affiliations

  1. National Radio Astronomy Observatory, Charlottesville, VA 22903, USA. Division of Chemistry and Chemical Engineering, California Institute of Technology Pasadena, CA 91125, USA. [email protected] [email protected].
  2. Division of Chemistry and Chemical Engineering, California Institute of Technology Pasadena, CA 91125, USA. [email protected] [email protected].
  3. Department of Astronomy, Harvard University, Cambridge, MA 02138, USA.
  4. Division of Chemistry and Chemical Engineering, California Institute of Technology Pasadena, CA 91125, USA.
  5. National Radio Astronomy Observatory, Charlottesville, VA 22903, USA.
  6. Division of Chemistry and Chemical Engineering, California Institute of Technology Pasadena, CA 91125, USA. Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA.

PMID: 27303055 DOI: 10.1126/science.aae0328

Abstract

Life on Earth relies on chiral molecules-that is, species not superimposable on their mirror images. This manifests itself in the selection of a single molecular handedness, or homochirality, across the biosphere. We present the astronomical detection of a chiral molecule, propylene oxide (CH3CHCH2O), in absorption toward the Galactic center. Propylene oxide is detected in the gas phase in a cold, extended molecular shell around the embedded, massive protostellar clusters in the Sagittarius B2 star-forming region. This material is representative of the earliest stage of solar system evolution in which a chiral molecule has been found.

Copyright © 2016, American Association for the Advancement of Science.

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