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Lipids. 1973 Nov;8(11):617-22. doi: 10.1007/BF02533144.

Leaf wax of oats.

Lipids

A P Tulloch, L L Hoffman

Affiliations

  1. Prairie Regional Laboratory, National Research Council, S7N 0W9, Saskatoon, Saskatchewan, Canada.

PMID: 27519760 DOI: 10.1007/BF02533144

Abstract

Leaf wax of oats (Kelsey variety) consists of hydrocarbons (5%), esters (10%), free alcohols (45%), free acids (2.5%), β-diketone (5.5%), hydroxy-β-diketones (2.5%), and unidentified (29%). Wax on leaf blades contains more free alcohols than wax on leaf sheaths, and wax on the flag leaf sheath contains more β-diketone than wax on the rest of the plant. Principal hydrocarbons are C29, C31, and C33. The esters, mainly C44-C48 and C52, are probably C18-C22 and C26 esters of hexacosanol. Free alcohols are almost entirely hexacosanol. The β-diketone is hentriacontane-14, 16-dione. Hydroxy β-diketones are a mixture of 5-, 6- and 7-hydroxyhentriacontane-14, 16-diones in the proportions 58∶35∶7. The wax also contains a small amount (0.5%) of 1,16-hexacosanediol.

References

  1. Science. 1967 Jun 9;156(3780):1322-35 - PubMed
  2. J Am Oil Chem Soc. 1966 Mar;43(3):153-6 - PubMed

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