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Chem Commun (Camb). 2016 Aug 18;52(69):10570-3. doi: 10.1039/c6cc04626f.

Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino-N-Boc-enamines.

Chemical communications (Cambridge, England)

Eiji Tayama, Yoshiaki Kobayashi, Yuka Toma

Affiliations

  1. Department of Chemistry, Faculty of Science, Niigata University, Niigata, 950-2181, Japan. [email protected].

PMID: 27498628 DOI: 10.1039/c6cc04626f

Abstract

Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino-N-Boc-enamines was demonstrated. The scope and limitation, experimental mechanistic studies, and a proposed reaction mechanism were also described.

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