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Dalton Trans. 2016 Oct 18;45(41):16157-16161. doi: 10.1039/c6dt02881k.

Oxygen reduction reaction catalyzed by nickel complexes based on thiophosphorylated calix[4]resorcinols and immobilized in the membrane electrode assembly of fuel cells.

Dalton transactions (Cambridge, England : 2003)

M K Kadirov, I R Knyazeva, I R Nizameev, R A Safiullin, V I Matveeva, K V Kholin, V V Khrizanforova, T I Ismaev, A R Burilov, Yu H Budnikova, O G Sinyashin

Affiliations

  1. A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 8, Akad. Arbuzov str., Kazan 420088, Russia. [email protected] and Kazan National Research Technological University, 68, K. Marx str., Kazan 420015, Russia.
  2. A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 8, Akad. Arbuzov str., Kazan 420088, Russia. [email protected].
  3. A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 8, Akad. Arbuzov str., Kazan 420088, Russia. [email protected] and Kazan National Research Technical University, 10, K. Marx str., Kazan 420111, Russia.
  4. Kazan National Research Technological University, 68, K. Marx str., Kazan 420015, Russia.

PMID: 27711779 DOI: 10.1039/c6dt02881k

Abstract

The catalytic activity of the nickel complexes of thiophosphorylated calix[4]resorcinols for oxygen reduction in a polymer electrolyte membrane fuel cell (PEMFC) has been studied. The conformation of the macrocyclic ligand determines the morphology and catalytic properties of the resulting organometallic species.

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