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Xu X, Liu Z, Yang S, et al. Potassium uranyl borate 3D framework compound resulted from temperature directed hydroborate condensation: structure, spectroscopy, and dissolution studies. Dalton Trans. 2016;45(39):15464-15472doi: 10.1039/c6dt03299k.
Xu, X., Liu, Z., Yang, S., Chen, L., Diwu, J., Alekseev, E. V., Chai, Z., Albrecht-Schmitt, T. E., & Wang, S. (2016). Potassium uranyl borate 3D framework compound resulted from temperature directed hydroborate condensation: structure, spectroscopy, and dissolution studies. Dalton transactions (Cambridge, England : 2003), 45(39), 15464-15472. https://doi.org/10.1039/c6dt03299k
Xu, Xiaomei, et al. "Potassium uranyl borate 3D framework compound resulted from temperature directed hydroborate condensation: structure, spectroscopy, and dissolution studies." Dalton transactions (Cambridge, England : 2003) vol. 45,39 (2016): 15464-15472. doi: https://doi.org/10.1039/c6dt03299k
Xu X, Liu Z, Yang S, Chen L, Diwu J, Alekseev EV, Chai Z, Albrecht-Schmitt TE, Wang S. Potassium uranyl borate 3D framework compound resulted from temperature directed hydroborate condensation: structure, spectroscopy, and dissolution studies. Dalton Trans. 2016 Oct 04;45(39):15464-15472. doi: 10.1039/c6dt03299k. PMID: 27711864.
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Dalton Trans. 2016 Oct 04;45(39):15464-15472. doi: 10.1039/c6dt03299k.

Potassium uranyl borate 3D framework compound resulted from temperature directed hydroborate condensation: structure, spectroscopy, and dissolution studies.

Dalton transactions (Cambridge, England : 2003)

Xiaomei Xu, Zhiyong Liu, Shitong Yang, Lanhua Chen, Juan Diwu, Evgeny V Alekseev, Zhifang Chai, Thomas E Albrecht-Schmitt, Shuao Wang

Affiliations

  1. School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Jiangsu 215123, China. [email protected].
  2. Institute of Energy and Climate Research (IEK-6), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany.
  3. Department of Chemistry and Biochemistry, Florida State University, 95 Chieftain Way, Tallahassee, Florida 32306, USA.

PMID: 27711864 DOI: 10.1039/c6dt03299k

Abstract

The equatorial coordination nature of the uranyl unit has resulted in only three uranyl borate 3D framework compounds reported so far formed from boric acid flux reactions conducted at 190 °C while all others are 2D layers. Here in this work, by increasing the reaction temperature to 250 °C, a new potassium uranyl borate K[(UO

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