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Suzuki N, Fujita T, Amsharov KY, et al. Aluminium-mediated aromatic C-F bond activation: regioswitchable construction of benzene-fused triphenylene frameworks. Chem Commun (Camb). 2016;52(88):12948-12951doi: 10.1039/c6cc07199f.
Suzuki, N., Fujita, T., Amsharov, K. Y., & Ichikawa, J. (2016). Aluminium-mediated aromatic C-F bond activation: regioswitchable construction of benzene-fused triphenylene frameworks. Chemical communications (Cambridge, England), 52(88), 12948-12951. https://doi.org/10.1039/c6cc07199f
Suzuki, Naoto, et al. "Aluminium-mediated aromatic C-F bond activation: regioswitchable construction of benzene-fused triphenylene frameworks." Chemical communications (Cambridge, England) vol. 52,88 (2016): 12948-12951. doi: https://doi.org/10.1039/c6cc07199f
Suzuki N, Fujita T, Amsharov KY, Ichikawa J. Aluminium-mediated aromatic C-F bond activation: regioswitchable construction of benzene-fused triphenylene frameworks. Chem Commun (Camb). 2016 Oct 27;52(88):12948-12951. doi: 10.1039/c6cc07199f. PMID: 27722478.
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Chem Commun (Camb). 2016 Oct 27;52(88):12948-12951. doi: 10.1039/c6cc07199f.

Aluminium-mediated aromatic C-F bond activation: regioswitchable construction of benzene-fused triphenylene frameworks.

Chemical communications (Cambridge, England)

Naoto Suzuki, Takeshi Fujita, Konstantin Yu Amsharov, Junji Ichikawa

Affiliations

  1. Division of Chemistry, Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan. [email protected].
  2. Institute of Organic Chemistry II, University of Erlangen-Nürnberg, Henkestr. 42, 91054 Erlangen, Germany.

PMID: 27722478 DOI: 10.1039/c6cc07199f

Abstract

Selective synthesis of benzo[f]tetraphenes or benzo[g]chrysenes was achieved via aromatic C-F bond cleavage and unprecedented regioselective C-C bond formation depending upon the choice of aluminium reagents. On treatment with AlCl

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