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Dalton Trans. 2016 Oct 25;45(42):16751-16763. doi: 10.1039/c6dt01754a.

Measuring giant anisotropy in paramagnetic transition metal complexes with relevance to single-ion magnetism.

Dalton transactions (Cambridge, England : 2003)

J Krzystek, Joshua Telser

Affiliations

  1. National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32310, USA. [email protected].
  2. Department of Biological, Chemical and Physical Sciences, Roosevelt University, Chicago, Illinois 60605, USA.

PMID: 27722619 DOI: 10.1039/c6dt01754a

Abstract

"Giant magnetic anisotropy" is a phenomenon identified fairly recently in coordination complexes of nd- and nf-block ions. It can have different origins but is commonly (if not always correctly) described through zero-field splitting (ZFS), which can reach values of 100 cm

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