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Kramer JK, Baumann WJ, Holman RT. Mass spectrometric analysis of long chain alk-1-enyl ether esters and alkyl ether esters of diols. Lipids. 1971;6(7):492-501doi: 10.1007/BF02531235.
Kramer, J. K., Baumann, W. J., & Holman, R. T. (1971). Mass spectrometric analysis of long chain alk-1-enyl ether esters and alkyl ether esters of diols. Lipids, 6(7), 492-501. https://doi.org/10.1007/BF02531235
Kramer, J K, et al. "Mass spectrometric analysis of long chain alk-1-enyl ether esters and alkyl ether esters of diols." Lipids vol. 6,7 (1971): 492-501. doi: https://doi.org/10.1007/BF02531235
Kramer JK, Baumann WJ, Holman RT. Mass spectrometric analysis of long chain alk-1-enyl ether esters and alkyl ether esters of diols. Lipids. 1971 Jul;6(7):492-501. doi: 10.1007/BF02531235. PMID: 27519359.
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Lipids. 1971 Jul;6(7):492-501. doi: 10.1007/BF02531235.

Mass spectrometric analysis of long chain alk-1-enyl ether esters and alkyl ether esters of diols.

Lipids

J K Kramer, W J Baumann, R T Holman

Affiliations

  1. The Hormel Institute, University of Minnesota, 55912, Austin, Minnesota.

PMID: 27519359 DOI: 10.1007/BF02531235

Abstract

The mass spectra of homologous series of long chain alk-1-enyl ether esters and alkyl ether esters of short chain diols were determined, and general patterns of fragmentation were established. Both types of diol lipids yielded ions characteristic of the alkoxy or alk-1-enyloxy moiety and the acyl moiety, as well as ions indicative of the constituent short chain diol. Prominent ions were formed from both types of ether esters due to the loss of the alkoxy or alk-1-enyloxy moieties giving rise to ions for which cyclic structures are proposed. High resolution mass spectrometry and deuterium labeling techniques were used to verify the composition of ions and to substantiate fragmentation mechanisms.

References

  1. Biochim Biophys Acta. 1970 Jun 9;210(1):7-14 - PubMed
  2. Lipids. 1971 Jul;6(7):502-7 - PubMed
  3. J Lipid Res. 1960 Oct;1:361-90 - PubMed
  4. Lipids. 1970 Nov;5(11):861-8 - PubMed
  5. Biochim Biophys Acta. 1967 Oct 2;144(2):355-65 - PubMed
  6. J Lipid Res. 1969 Nov;10(6):703-9 - PubMed
  7. Chem Phys Lipids. 1968 Feb;2(1):114-28 - PubMed
  8. Science. 1969 Nov 28;166(3909):1158-9 - PubMed
  9. Lipids. 1970 Nov;5(11):869-77 - PubMed
  10. Hoppe Seylers Z Physiol Chem. 1968 Dec;349(12):1677-85 - PubMed
  11. Biochim Biophys Acta. 1966 Jun 1;116(3):511-20 - PubMed
  12. Biochim Biophys Acta. 1961 Dec 9;54:359-60 - PubMed
  13. Lipids. 1969 Nov;4(6):421-7 - PubMed
  14. J Org Chem. 1965 Dec;30(12):4168-75 - PubMed

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