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Eijsink LE, Perdriau SC, de Vries JG, et al. Metal-ligand cooperative activation of nitriles by a ruthenium complex with a de-aromatized PNN pincer ligand. Dalton Trans. 2016;45(40):16033-16039doi: 10.1039/c6dt02478e.
Eijsink, L. E., Perdriau, S. C., de Vries, J. G., & Otten, E. (2016). Metal-ligand cooperative activation of nitriles by a ruthenium complex with a de-aromatized PNN pincer ligand. Dalton transactions (Cambridge, England : 2003), 45(40), 16033-16039. https://doi.org/10.1039/c6dt02478e
Eijsink, Linda E, et al. "Metal-ligand cooperative activation of nitriles by a ruthenium complex with a de-aromatized PNN pincer ligand." Dalton transactions (Cambridge, England : 2003) vol. 45,40 (2016): 16033-16039. doi: https://doi.org/10.1039/c6dt02478e
Eijsink LE, Perdriau SC, de Vries JG, Otten E. Metal-ligand cooperative activation of nitriles by a ruthenium complex with a de-aromatized PNN pincer ligand. Dalton Trans. 2016 Oct 12;45(40):16033-16039. doi: 10.1039/c6dt02478e. PMID: 27727356.
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Dalton Trans. 2016 Oct 12;45(40):16033-16039. doi: 10.1039/c6dt02478e.

Metal-ligand cooperative activation of nitriles by a ruthenium complex with a de-aromatized PNN pincer ligand.

Dalton transactions (Cambridge, England : 2003)

Linda E Eijsink, Sébastien C P Perdriau, Johannes G de Vries, Edwin Otten

Affiliations

  1. Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands. [email protected].
  2. Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands. [email protected] and Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.

PMID: 27727356 DOI: 10.1039/c6dt02478e

Abstract

The pincer complex (PNN)RuH(CO), with a de-aromatized pyridine in the ligand backbone, is shown to react with nitriles in a metal-ligand cooperative manner. This leads to the formation of a series of complexes with new Ru-N(nitrile) and C(ligand)-C(nitrile) bonds. The initial nitrile cycloaddition products, the ketimido complexes 3, have a Brønsted basic (nitrile-derived) Ru-N fragment. This is able to deprotonate a CH

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