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J Am Chem Soc. 2016 Oct 26;138(42):13941-13951. doi: 10.1021/jacs.6b06989. Epub 2016 Oct 12.

Examining the Effects of Ligand Variation on the Electronic Structure of Uranium Bis(imido) Species.

Journal of the American Chemical Society

John J Kiernicki, Maryline G Ferrier, Juan S Lezama Pacheco, Henry S La Pierre, Benjamin W Stein, Matthias Zeller, Stosh A Kozimor, Suzanne C Bart

Affiliations

  1. H.C. Brown Laboratory, Department of Chemistry, Purdue University , West Lafayette, Indiana 47907, United States.
  2. Los Alamos National Laboratory , Los Alamos, New Mexico 87545, United States.
  3. Stanford University , Stanford, California 94305, United States.
  4. Department of Chemistry, Youngstown State University , Youngstown, Ohio 44555, United States.

PMID: 27731988 DOI: 10.1021/jacs.6b06989

Abstract

Arylazide and diazene activation by highly reduced uranium(IV) complexes bearing trianionic redox-active pyridine(diimine) ligands, [Cp

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