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J Am Chem Soc. 2016 Dec 21;138(50):16459-16465. doi: 10.1021/jacs.6b10394. Epub 2016 Dec 12.

Silver(I)-Mediated Modification, Dimerization, and Polymerization of an Open-Cage Fullerene.

Journal of the American Chemical Society

Amineh Aghabali, Sharon Jun, Marilyn M Olmstead, Alan L Balch

Affiliations

  1. Department of Chemistry, University of California at Davis , One Shields Avenue, Davis, California 95616, United States.

PMID: 27936651 DOI: 10.1021/jacs.6b10394

Abstract

The reactions of the open-cage fullerene, MMK-9, with an open 12-membered ring on its surface and silver(I) salts have been examined. The structure of MMK-9 itself has been determined by single-crystal X-ray diffraction. MMK-9 reacts with silver trifluoroacetate in air to form the dimer, {MMK-9(OCH

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