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J Am Chem Soc. 2016 Dec 21;138(50):16337-16344. doi: 10.1021/jacs.6b09209. Epub 2016 Dec 07.

Energy Gap between the Poly-p-phenylene Bridge and Donor Groups Controls the Hole Delocalization in Donor-Bridge-Donor Wires.

Journal of the American Chemical Society

Denan Wang, Marat R Talipov, Maxim V Ivanov, Rajendra Rathore

Affiliations

  1. Department of Chemistry, Marquette University , P.O. Box 1881, Milwaukee, Wisconsin 53201-1881, United States.

PMID: 27998092 DOI: 10.1021/jacs.6b09209

Abstract

Poly-p-phenylene wires are critically important as charge-transfer materials in photovoltaics. A comparative analysis of a series of poly-p-phenylene (

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