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Justyniak I, Prochowicz D, Tulewicz A, et al. Structure investigations of group 13 organometallic carboxylates. Dalton Trans. 2017;46(3):669-677doi: 10.1039/c6dt03958h.
Justyniak, I., Prochowicz, D., Tulewicz, A., Bury, W., Goś, P., & Lewiński, J. (2017). Structure investigations of group 13 organometallic carboxylates. Dalton transactions (Cambridge, England : 2003), 46(3), 669-677. https://doi.org/10.1039/c6dt03958h
Justyniak, Iwona, et al. "Structure investigations of group 13 organometallic carboxylates." Dalton transactions (Cambridge, England : 2003) vol. 46,3 (2017): 669-677. doi: https://doi.org/10.1039/c6dt03958h
Justyniak I, Prochowicz D, Tulewicz A, Bury W, Goś P, Lewiński J. Structure investigations of group 13 organometallic carboxylates. Dalton Trans. 2017 Jan 17;46(3):669-677. doi: 10.1039/c6dt03958h. PMID: 27966728.
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Dalton Trans. 2017 Jan 17;46(3):669-677. doi: 10.1039/c6dt03958h.

Structure investigations of group 13 organometallic carboxylates.

Dalton transactions (Cambridge, England : 2003)

Iwona Justyniak, Daniel Prochowicz, Adam Tulewicz, Wojciech Bury, Piotr Goś, Janusz Lewiński

Affiliations

  1. Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland. [email protected].
  2. Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland.
  3. Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland and Faculty of Chemistry, University of Wroc?aw, 14 F. Joliot-Curie, Wroc?aw, Poland.
  4. Department of Inorganic and Analytical Chemistry, Faculty of Pharmacy, Medical University of Warsaw, Banacha 1, 02-097 Warsaw, Poland.
  5. Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland. [email protected] and Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland.

PMID: 27966728 DOI: 10.1039/c6dt03958h

Abstract

The octet-compliant group 13 organometallics with highly polarized bonds in the metal coordination sphere exhibit a significant tendency to maximize their coordination number through the formation of adducts with a wide range of neutral donor ligands or by self-association to give aggregates containing tetrahedral and higher coordinated aluminium centres, and even in some cases molecular complexes equilibrate with ionic species of different coordination numbers of the metal centre. This work provides a comprehensive overview of the structural chemistry landscape of the group 13 carboxylates. Aside from a more systematic approach to the general structural chemistry of the title compounds, the structure investigations of [R

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