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Eguillor B, Esteruelas MA, Lezáun V, et al. Elongated Dihydrogen versus Compressed Dihydride in Osmium Complexes. Chemistry. 2017;23(7):1526-1530doi: 10.1002/chem.201605843.
Eguillor, B., Esteruelas, M. A., Lezáun, V., Oliván, M., & Oñate, E. (2017). Elongated Dihydrogen versus Compressed Dihydride in Osmium Complexes. Chemistry (Weinheim an der Bergstrasse, Germany), 23(7), 1526-1530. https://doi.org/10.1002/chem.201605843
Eguillor, Beatriz, et al. "Elongated Dihydrogen versus Compressed Dihydride in Osmium Complexes." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 23,7 (2017): 1526-1530. doi: https://doi.org/10.1002/chem.201605843
Eguillor B, Esteruelas MA, Lezáun V, Oliván M, Oñate E. Elongated Dihydrogen versus Compressed Dihydride in Osmium Complexes. Chemistry. 2017 Jan 31;23(7):1526-1530. doi: 10.1002/chem.201605843. Epub 2017 Jan 12. PMID: 27991701.
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Chemistry. 2017 Jan 31;23(7):1526-1530. doi: 10.1002/chem.201605843. Epub 2017 Jan 12.

Elongated Dihydrogen versus Compressed Dihydride in Osmium Complexes.

Chemistry (Weinheim an der Bergstrasse, Germany)

Beatriz Eguillor, Miguel A Esteruelas, Virginia Lezáun, Montserrat Oliván, Enrique Oñate

Affiliations

  1. Departamento de Química Inorgánica, Instituto de Síntesis QuímicayCatálisis Homogénea (ISQCH), Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universidad de Zaragoza-CSIC, 50009, Zaragoza, Spain.

PMID: 27991701 DOI: 10.1002/chem.201605843

Abstract

Small modifications on the co-ligands of complexes containing two coordinated hydrogen atoms can determine the elongated dihydrogen versus compressed dihydride nature of these species and therefore their chemical behavior. 2,6-diphenylpyridine favors the formation of the osmium(IV) cation [OsH

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: C−H activation; agostic interactions; dihydrogen; hydrides; osmium

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