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Qiao S, Mo J, Wilcox CB, et al. Chiral GAP catalysts of phosphonylated imidazolidinones and their applications in asymmetric Diels-Alder and Friedel-Crafts reactions. Org Biomol Chem. 2017;15(7):1718-1724doi: 10.1039/c6ob02801b.
Qiao, S., Mo, J., Wilcox, C. B., Jiang, B., & Li, G. (2017). Chiral GAP catalysts of phosphonylated imidazolidinones and their applications in asymmetric Diels-Alder and Friedel-Crafts reactions. Organic & biomolecular chemistry, 15(7), 1718-1724. https://doi.org/10.1039/c6ob02801b
Qiao, Shuo, et al. "Chiral GAP catalysts of phosphonylated imidazolidinones and their applications in asymmetric Diels-Alder and Friedel-Crafts reactions." Organic & biomolecular chemistry vol. 15,7 (2017): 1718-1724. doi: https://doi.org/10.1039/c6ob02801b
Qiao S, Mo J, Wilcox CB, Jiang B, Li G. Chiral GAP catalysts of phosphonylated imidazolidinones and their applications in asymmetric Diels-Alder and Friedel-Crafts reactions. Org Biomol Chem. 2017 Feb 21;15(7):1718-1724. doi: 10.1039/c6ob02801b. Epub 2017 Jan 31. PMID: 28139798; PMCID: PMC5323037.
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Org Biomol Chem. 2017 Feb 21;15(7):1718-1724. doi: 10.1039/c6ob02801b. Epub 2017 Jan 31.

Chiral GAP catalysts of phosphonylated imidazolidinones and their applications in asymmetric Diels-Alder and Friedel-Crafts reactions.

Organic & biomolecular chemistry

Shuo Qiao, Junming Mo, Cody B Wilcox, Bo Jiang, Guigen Li

Affiliations

  1. Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas 79409-1061, USA. [email protected].

PMID: 28139798 PMCID: PMC5323037 DOI: 10.1039/c6ob02801b

Abstract

The design and synthesis of recyclable imidazolidinone catalysts using GAP chemistry/technique was described. Their applications in asymmetric Diels-Alder and Friedel-Crafts reactions with α,β-unsaturated aldehydes resulted in excellent yields and higher enantioselectivities than previous processes. As recyclable small molecular catalysts, phosphonylated imidazolidinones can be recovered and reused for up to three runs without costing significant decrease in catalytic activity.

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