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Chem Commun (Camb). 2017 Feb 02;53(11):1852-1855. doi: 10.1039/c6cc09080j.

Palladium-catalyzed synthesis of [60]fullerene-fused benzofurans via heteroannulation of phenols.

Chemical communications (Cambridge, England)

Fei Li, Jun-Jie Wang, Guan-Wu Wang

Affiliations

  1. CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China. [email protected] and Department of Chemistry, Anhui University, Hefei, Anhui 230039, P. R. China.
  2. CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China. [email protected].
  3. CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China. [email protected] and State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, Gansu 730000, P. R. China.

PMID: 28111656 DOI: 10.1039/c6cc09080j

Abstract

Palladium-catalyzed heteroannulation of [60]fullerene with phenols has been developed as a practical and efficient protocol for the one-pot synthesis of various [60]fullerene-fused benzofurans. A possible reaction mechanism is proposed to explain the formation of C

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