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ChemistryOpen. 2017 Jan 09;6(1):25-32. doi: 10.1002/open.201600139. eCollection 2017 Feb.

Self-Supported Polypyrrole/Polyvinylsulfate Films: Electrochemical Synthesis, Characterization, and Sensing Properties of Their Redox Reactions.

ChemistryOpen

Toribio F Otero, Lluis X Martinez-Soria, Johanna Schumacher, Laura Valero, Victor H Pascual

Affiliations

  1. Centre for Electrochemistry and Intelligent Materials (CEMI) Universidad Politécnica de Cartagena (UPCT) Aulario II 30203 Cartagena Spain.
  2. Arquimea Ingeniería S.L.U. Calle Margarita Salas, 10 (Pol Ind Leganec) 28918 Leganés Madrid Spain.
  3. Centre for Electrochemistry and Intelligent Materials (CEMI) Universidad Politécnica de Cartagena (UPCT) Aulario II 30203 Cartagena Spain; Engineering School Universidad Autónoma del Estado de México Toluca 50000 Mexico.

PMID: 28168147 PMCID: PMC5288749 DOI: 10.1002/open.201600139

Abstract

Thick films of polypyrrole/polyvinylsulfate (PPy/PVS) blends were electrogenerated on stainless-steel electrodes under potentiostatic conditions from aqueous solution. The best electropolymerization potential window was determined by cyclic voltammetry. After removing the film from the back metal, self-supported electrodes were obtained. Voltammetric, coulovoltammetric, and chronoamperometric responses from a LiClO

Keywords: conducting materials; coulovoltammetry; electrochemistry; lamellar structures; polymer composites

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