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Dalton Trans. 2017 Apr 11;46(15):4912-4916. doi: 10.1039/c7dt00468k.

A novel symmetric TTF-pyridyl thiolato zinc complex: synthesis, characterization and crystal structure analysis.

Dalton transactions (Cambridge, England : 2003)

Ryota Okuno, Minayo Yamaguchi, Hideki Fujiwara

Affiliations

  1. Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Gakuen-cho, Naka-ku, Sakai 599-8531, Japan. [email protected].

PMID: 28345714 DOI: 10.1039/c7dt00468k

Abstract

We report the first preparation of a symmetric tetrathiafulvalene (TTF)-pyridyl thiolato zinc(ii) complex in which two TTF parts connect to the central zinc atom through pyridines and thiolates. We also discuss the crystal structure analysis and physical properties of the complex, especially photocurrent generations measured on its thin-film sample and single crystal.

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