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Inorg Chem. 2017 Apr 17;56(8):4271-4279. doi: 10.1021/acs.inorgchem.6b02098. Epub 2017 Mar 27.

Canted Antiferromagnetism on Rectangular Layers of Fe.

Inorganic chemistry

Kwing To Lai, Alexander Christoph Komarek, Maria Teresa Fernández-Díaz, Pi-Shan Chang, Sungjoon Huh, Helge Rosner, Chang-Yang Kuo, Zhiwei Hu, Tun-Wen Pi, Peter Adler, Vadim Ksenofontov, Liu Hao Tjeng, Martin Valldor

Affiliations

  1. Max Planck Institute for Chemical Physics of Solids , Nöthnitzer Straße 40, 01187 Dresden, Germany.
  2. Institute Laue Langevin , 71 Avenue des Martyrs, 39042 Grenoble Cedex 9, France.
  3. Department of Electrophysics, National Chiao Tung University , HsinChu 30100, Taiwan.
  4. University of British Colombia , 2329 West Mall, Vancouver, BC V6T 1Z4, Canada.
  5. National Synchrotron Radiation Research Centre , Hsinchu 30076, Taiwan.
  6. Institut für Anorganische und Analytische Chemie, Johannes Gutenberg-Universität , 55128 Mainz, Germany.

PMID: 28345884 DOI: 10.1021/acs.inorgchem.6b02098

Abstract

From stoichiometric amounts of CaO, Fe, and Se, pure powders and single crystals of quaternary [Formula: see text] can be obtained by solid-state reaction and self-flux growth, respectively. The as-synthesized compound exhibits a polymorphic crystal structure, where the two modifications have different stacking sequences of [Formula: see text] layers. The two polymorphs have similar unit cells but different crystal symmetries (Cmc2

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