Display options
Share it on

Solid State Nucl Magn Reson. 2017 Sep;85:1-11. doi: 10.1016/j.ssnmr.2017.01.004. Epub 2017 Jan 29.

Monitoring a simple hydrolysis process in an organic solid by observing methyl group rotation.

Solid state nuclear magnetic resonance

Peter A Beckmann, Joseph M Bohen, Jamie Ford, William P Malachowski, Clelia W Mallory, Frank B Mallory, Andrew R McGhie, Arnold L Rheingold, Gilbert J Sloan, Steven T Szewczyk, Xianlong Wang, Kraig A Wheeler

Affiliations

  1. Department of Physics, Bryn Mawr College, 101 North Merion Ave., Bryn Mawr, PA 19010-2899, USA. Electronic address: [email protected].
  2. Department of Chemistry, Bryn Mawr College, 101 North Merion Ave., Bryn Mawr, PA 19010-2899, USA.
  3. Nanoscale Characterization Facility, Singh Center for Nanotechnology, University of Pennsylvania, 3205 Walnut St., Philadelphia, PA 19104-3405, USA.
  4. Department of Chemistry, University of Pennsylvania, 231 South 34 Street, Philadelphia, PA 19104-6323, USA.
  5. Laboratory for Research on the Structure of Matter, University of Pennsylvania, 3231 Walnut St., Philadelphia, PA 19104-6202, USA.
  6. Department of Chemistry and Biochemistry, University of California, San Diego, 5128 Urey Hall, 9500 Gilman Dr., La Jolla, CA 92093-0358, USA.
  7. Department of Materials Science and Engineering, School of Engineering and Applied Science, University of Pennsylvania, 3231 Walnut St., Philadelphia, PA 19104-6202, USA.
  8. Key Laboratory for NeuroInformation of Ministry of Education, School of Life Science and Technology, University of Electronic Science and Technology of China, 4 North Jianshe Rd., 22nd Section, Chengdu 610054, China.
  9. Department of Chemistry, Eastern Illinois University, 600 Lincoln Ave., Charleston, IL 69120-3099, USA.

PMID: 28260612 DOI: 10.1016/j.ssnmr.2017.01.004

Abstract

We report a variety of experiments and calculations and their interpretations regarding methyl group (CH

Copyright © 2017 Elsevier Inc. All rights reserved.

Keywords: Chemical conversion by hydrolysis; Electronic structure calculations in molecular clusters; Methyl group rotation; Molecular solids; Scanning electron microscopy in organics; Single-crystal X-ray diffraction

Publication Types