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J Am Chem Soc. 2017 Apr 19;139(15):5520-5529. doi: 10.1021/jacs.7b01460. Epub 2017 Apr 06.

Subphthalocyanines Axially Substituted with a Tetracyanobuta-1,3-diene-Aniline Moiety: Synthesis, Structure, and Physicochemical Properties.

Journal of the American Chemical Society

Kim A Winterfeld, Giulia Lavarda, Julia Guilleme, Michael Sekita, Dirk M Guldi, Tomás Torres, Giovanni Bottari

Affiliations

  1. Department of Chemistry and Pharmacy, Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg , Egerlandstr. 3, 91058 Erlangen, Germany.
  2. Departamento de Química Orgánica, Universidad Autónoma de Madrid , 28049 Madrid, Spain.
  3. IMDEA-Nanociencia , Campus de Cantoblanco, 28049 Madrid, Spain.
  4. Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid , 28049 Madrid, Spain.

PMID: 28322560 DOI: 10.1021/jacs.7b01460

Abstract

A 1,1,4,4-tetracyanobuta-1,3-diene (TCBD)-aniline moiety has been introduced, for the first time, at the axial position of two subphthalocyanines (SubPcs) peripherally substituted with hydrogen (H

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