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Guérin J, Léaustic A, Berthet J, et al. Light-Controlled Release and Uptake of Zinc Ions in Solution by a Photochromic Terthiazole-Based Ligand. Chem Asian J. 2017;12(8):853-859doi: 10.1002/asia.201700028.
Guérin, J., Léaustic, A., Berthet, J., Métivier, R., Guillot, R., Delbaere, S., Nakatani, K., & Yu, P. (2017). Light-Controlled Release and Uptake of Zinc Ions in Solution by a Photochromic Terthiazole-Based Ligand. Chemistry, an Asian journal, 12(8), 853-859. https://doi.org/10.1002/asia.201700028
Guérin, Juliette, et al. "Light-Controlled Release and Uptake of Zinc Ions in Solution by a Photochromic Terthiazole-Based Ligand." Chemistry, an Asian journal vol. 12,8 (2017): 853-859. doi: https://doi.org/10.1002/asia.201700028
Guérin J, Léaustic A, Berthet J, Métivier R, Guillot R, Delbaere S, Nakatani K, Yu P. Light-Controlled Release and Uptake of Zinc Ions in Solution by a Photochromic Terthiazole-Based Ligand. Chem Asian J. 2017 Apr 18;12(8):853-859. doi: 10.1002/asia.201700028. Epub 2017 Mar 22. PMID: 28328111.
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Chem Asian J. 2017 Apr 18;12(8):853-859. doi: 10.1002/asia.201700028. Epub 2017 Mar 22.

Light-Controlled Release and Uptake of Zinc Ions in Solution by a Photochromic Terthiazole-Based Ligand.

Chemistry, an Asian journal

Juliette Guérin, Anne Léaustic, Jérôme Berthet, Rémi Métivier, Régis Guillot, Stéphanie Delbaere, Keitaro Nakatani, Pei Yu

Affiliations

  1. Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), CNRS, Univ Paris Sud, Université Paris-Saclay, 91405, Orsay, France.
  2. LASIR, Université de Lille, CNRS, 59000, Lille, France.
  3. PPSM, ENS Cachan, Université Paris-Saclay, 61 av. Président Wilson, 94235, Cachan, France.

PMID: 28328111 DOI: 10.1002/asia.201700028

Abstract

We have synthesized and fully characterized a photochromic zinc complex with a terphenylthiazole-based ligand with a salen-like cavity. The solution stability of the complex was found to be greatly dependent on the state of the photochromic ligand and an interesting photo-triggered release and uptake of zinc ions was found as well as monitored by its fluorescence. The contrasting stability difference of the zinc complex between its two isomeric states was rationalized by DFT calculations.

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: density functional theory; fluorescence; metalation; photo-switching; photochromism

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