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J Org Chem. 2017 May 05;82(9):4859-4865. doi: 10.1021/acs.joc.7b00580. Epub 2017 Apr 20.

Pd-Boron-Catalyzed One Carbon Isomerization of Olefins: Water Assisted Process at Room Temperature.

The Journal of organic chemistry

Devi Prasan Ojha, Karthik Gadde, Kandikere Ramaiah Prabhu

Affiliations

  1. Department of Organic Chemistry, Indian Institute of Science , Bangalore, 560012 Karnataka, India.

PMID: 28402642 DOI: 10.1021/acs.joc.7b00580

Abstract

A palladium-boronate/borane-system -catalyzed isomerization of olefins has been uncovered. An efficient catalytic combination of [Pd(OAc)

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