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Mirabelli MF, Wolf JC, Zenobi R. Atmospheric pressure soft ionization for gas chromatography with dielectric barrier discharge ionization-mass spectrometry (GC-DBDI-MS). Analyst. 2017;142(11):1909-1915doi: 10.1039/c7an00245a.
Mirabelli, M. F., Wolf, J. C., & Zenobi, R. (2017). Atmospheric pressure soft ionization for gas chromatography with dielectric barrier discharge ionization-mass spectrometry (GC-DBDI-MS). The Analyst, 142(11), 1909-1915. https://doi.org/10.1039/c7an00245a
Mirabelli, Mario F, et al. "Atmospheric pressure soft ionization for gas chromatography with dielectric barrier discharge ionization-mass spectrometry (GC-DBDI-MS)." The Analyst vol. 142,11 (2017): 1909-1915. doi: https://doi.org/10.1039/c7an00245a
Mirabelli MF, Wolf JC, Zenobi R. Atmospheric pressure soft ionization for gas chromatography with dielectric barrier discharge ionization-mass spectrometry (GC-DBDI-MS). Analyst. 2017 May 30;142(11):1909-1915. doi: 10.1039/c7an00245a. PMID: 28443843.
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Analyst. 2017 May 30;142(11):1909-1915. doi: 10.1039/c7an00245a.

Atmospheric pressure soft ionization for gas chromatography with dielectric barrier discharge ionization-mass spectrometry (GC-DBDI-MS).

The Analyst

Mario F Mirabelli, Jan-Christoph Wolf, Renato Zenobi

Affiliations

  1. ETH Zurich, Department of Chemistry and Applied Biosciences, CH-8093 Zürich, Switzerland. [email protected].

PMID: 28443843 DOI: 10.1039/c7an00245a

Abstract

In this study, a gas chromatography (GC) system was interfaced to a high-resolution Orbitrap mass spectrometer by means of an active capillary plasma ionization source, based on dielectric barrier discharge ionization (DBDI). This allowed highly efficient soft ionization of gas-phase, chromatographically resolved compounds at ambient pressure. Several pesticides and illicit drugs were analyzed, and the limits of detections (LODs) were as low as 30 pg mL

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