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Reusch E, Holzmeier F, Constantinidis P, et al. Isomer-Selective Generation and Spectroscopic Characterization of Picolyl Radicals. Angew Chem Int Ed Engl. 2017;56(27):8000-8003doi: 10.1002/anie.201703433.
Reusch, E., Holzmeier, F., Constantinidis, P., Hemberger, P., & Fischer, I. (2017). Isomer-Selective Generation and Spectroscopic Characterization of Picolyl Radicals. Angewandte Chemie (International ed. in English), 56(27), 8000-8003. https://doi.org/10.1002/anie.201703433
Reusch, Engelbert, et al. "Isomer-Selective Generation and Spectroscopic Characterization of Picolyl Radicals." Angewandte Chemie (International ed. in English) vol. 56,27 (2017): 8000-8003. doi: https://doi.org/10.1002/anie.201703433
Reusch E, Holzmeier F, Constantinidis P, Hemberger P, Fischer I. Isomer-Selective Generation and Spectroscopic Characterization of Picolyl Radicals. Angew Chem Int Ed Engl. 2017 Jun 26;56(27):8000-8003. doi: 10.1002/anie.201703433. Epub 2017 Jun 06. PMID: 28508574.
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Angew Chem Int Ed Engl. 2017 Jun 26;56(27):8000-8003. doi: 10.1002/anie.201703433. Epub 2017 Jun 06.

Isomer-Selective Generation and Spectroscopic Characterization of Picolyl Radicals.

Angewandte Chemie (International ed. in English)

Engelbert Reusch, Fabian Holzmeier, Philipp Constantinidis, Patrick Hemberger, Ingo Fischer

Affiliations

  1. Institut für Physikalische und Theoretische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
  2. Present address: Institut des Sciences Moléculaires d'Orsay ISMO (UMR 8214 CNRS), Bâtiment 350, Université Paris-Saclay, 91405, Orsay Cedex, France.
  3. Laboratory for Femtochemistry and Synchrotron Radiation, Paul Scherrer Institut (PSI), 5232, Villigen, Switzerland.

PMID: 28508574 DOI: 10.1002/anie.201703433

Abstract

Nitrogen-containing resonance-stabilized radicals such as the picolyl radical are important in combustion chemistry and astrochemistry. They have only been scarcely studied because an isomer-selective generation is often difficult. Herein, we present threshold photoelectron spectra of the three picolyl radical isomers, C

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: high-temperature chemistry; ionization potentials; photoelectron spectroscopy; radicals; synchrotron radiation

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