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Qin B, Zhang S, Song Q, et al. Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials. Angew Chem Int Ed Engl. 2017;56(26):7639-7643doi: 10.1002/anie.201703572.
Qin, B., Zhang, S., Song, Q., Huang, Z., Xu, J. F., & Zhang, X. (2017). Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials. Angewandte Chemie (International ed. in English), 56(26), 7639-7643. https://doi.org/10.1002/anie.201703572
Qin, Bo, et al. "Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials." Angewandte Chemie (International ed. in English) vol. 56,26 (2017): 7639-7643. doi: https://doi.org/10.1002/anie.201703572
Qin B, Zhang S, Song Q, Huang Z, Xu JF, Zhang X. Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials. Angew Chem Int Ed Engl. 2017 Jun 19;56(26):7639-7643. doi: 10.1002/anie.201703572. Epub 2017 May 24. PMID: 28480605; PMCID: PMC5488215.
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Angew Chem Int Ed Engl. 2017 Jun 19;56(26):7639-7643. doi: 10.1002/anie.201703572. Epub 2017 May 24.

Supramolecular Interfacial Polymerization: A Controllable Method of Fabricating Supramolecular Polymeric Materials.

Angewandte Chemie (International ed. in English)

Bo Qin, Shuai Zhang, Qiao Song, Zehuan Huang, Jiang-Fei Xu, Xi Zhang

Affiliations

  1. Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, China.

PMID: 28480605 PMCID: PMC5488215 DOI: 10.1002/anie.201703572

Abstract

A new method of supramolecular polymerization at the water-oil interface is developed. As a demonstration, an oil-soluble supramonomer containing two thiol end groups linked by two ureidopyrimidinone units and a water-soluble monomer bearing two maleimide end groups are employed. Supramolecular interfacial polymerization can be implemented by a thiol-maleimide click reaction at the water-chloroform interface to obtain supramolecular polymeric films. The glass transition temperature of such supramolecular polymers can be well-tuned by simply changing the polymerization time and temperature. It is highly anticipated that this work will provide a facile and general approach to realize control over supramolecular polymerization by transferring the preparation of supramolecular polymers from solutions to water-oil interfaces and construct supramolecular materials with well-defined properties.

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: hydrogen bonds; interfacial polymerization; self-assembly; supramolecular chemistry; supramolecular polymers

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