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Lancel G, Stevens P, Toussaint G, et al. Hybrid Li Ion Conducting Membrane as Protection for the Li Anode in an Aqueous Li-Air Battery: Coupling Sol-Gel Chemistry and Electrospinning. Langmuir. 2017;33(37):9288-9297doi: 10.1021/acs.langmuir.7b00675.
Lancel, G., Stevens, P., Toussaint, G., Maréchal, M., Krins, N., Bregiroux, D., & Laberty-Robert, C. (2017). Hybrid Li Ion Conducting Membrane as Protection for the Li Anode in an Aqueous Li-Air Battery: Coupling Sol-Gel Chemistry and Electrospinning. Langmuir : the ACS journal of surfaces and colloids, 33(37), 9288-9297. https://doi.org/10.1021/acs.langmuir.7b00675
Lancel, Gilles, et al. "Hybrid Li Ion Conducting Membrane as Protection for the Li Anode in an Aqueous Li-Air Battery: Coupling Sol-Gel Chemistry and Electrospinning." Langmuir : the ACS journal of surfaces and colloids vol. 33,37 (2017): 9288-9297. doi: https://doi.org/10.1021/acs.langmuir.7b00675
Lancel G, Stevens P, Toussaint G, Maréchal M, Krins N, Bregiroux D, Laberty-Robert C. Hybrid Li Ion Conducting Membrane as Protection for the Li Anode in an Aqueous Li-Air Battery: Coupling Sol-Gel Chemistry and Electrospinning. Langmuir. 2017 Sep 19;33(37):9288-9297. doi: 10.1021/acs.langmuir.7b00675. Epub 2017 May 17. PMID: 28482152.
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Langmuir. 2017 Sep 19;33(37):9288-9297. doi: 10.1021/acs.langmuir.7b00675. Epub 2017 May 17.

Hybrid Li Ion Conducting Membrane as Protection for the Li Anode in an Aqueous Li-Air Battery: Coupling Sol-Gel Chemistry and Electrospinning.

Langmuir : the ACS journal of surfaces and colloids

Gilles Lancel, Philippe Stevens, Gwenaëlle Toussaint, Manuel Maréchal, Natacha Krins, Damien Bregiroux, Christel Laberty-Robert

Affiliations

  1. Sorbonne Universités , UPMC Univ Paris 06, CNRS, Collège de France, Laboratoire de Chimie de la Matière Condensée de Paris, 4 place Jussieu, 75005 Paris, France.
  2. EDF R&D, 77818 Moret Sur Loing, Cedex, France.
  3. Univ. Grenoble Alpes , CNRS, CEA, INAC, SYMMES, F-38000 Grenoble, France.

PMID: 28482152 DOI: 10.1021/acs.langmuir.7b00675

Abstract

Aqueous lithium-air batteries have very high theoretical energy densities, which potentially makes this technology very interesting for energy storage in electric mobility applications. However, the aqueous electrolyte requires the use of a watertight layer to protect the lithium metal, typically a thick NASICON glass-ceramic layer, which adds ohmic resistance and penalizes performance. This article deals with the replacement of this ceramic electrolyte by a hybrid organic-inorganic membrane. This new membrane combines an ionically conducting inorganic phase for Li ion transport (Li

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