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Gandeepan P, Mo J, Ackermann L. Photo-induced copper-catalyzed C-H chalcogenation of azoles at room temperature. Chem Commun (Camb). 2017;53(43):5906-5909doi: 10.1039/c7cc03107f.
Gandeepan, P., Mo, J., & Ackermann, L. (2017). Photo-induced copper-catalyzed C-H chalcogenation of azoles at room temperature. Chemical communications (Cambridge, England), 53(43), 5906-5909. https://doi.org/10.1039/c7cc03107f
Gandeepan, Parthasarathy, et al. "Photo-induced copper-catalyzed C-H chalcogenation of azoles at room temperature." Chemical communications (Cambridge, England) vol. 53,43 (2017): 5906-5909. doi: https://doi.org/10.1039/c7cc03107f
Gandeepan P, Mo J, Ackermann L. Photo-induced copper-catalyzed C-H chalcogenation of azoles at room temperature. Chem Commun (Camb). 2017 May 30;53(43):5906-5909. doi: 10.1039/c7cc03107f. PMID: 28513650.
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Chem Commun (Camb). 2017 May 30;53(43):5906-5909. doi: 10.1039/c7cc03107f.

Photo-induced copper-catalyzed C-H chalcogenation of azoles at room temperature.

Chemical communications (Cambridge, England)

Parthasarathy Gandeepan, Jiayu Mo, Lutz Ackermann

Affiliations

  1. Institut für Organische und Biomolekulare Chemie, Georg-August-Universität, Tammannstraße 2, 37077 Goettingen, Germany. [email protected].

PMID: 28513650 DOI: 10.1039/c7cc03107f

Abstract

Inexpensive copper catalysts enabled direct C-H chalcogenations at ambient temperature by means of photo-induced catalysis. The expedient copper catalysis set the stage for C-S and C-Se bond formation from readily accessible non-volatile elemental chalcogens. The photo-assisted copper catalysis manifold proved suitable for a wide range of substrates with good functional group tolerance and exhibited high catalytic efficacy even at a reaction temperature of 25 °C.

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