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Guo F, Yang P, Pan Z, et al. Carbon-Doped BN Nanosheets for the Oxidative Dehydrogenation of Ethylbenzene. Angew Chem Int Ed Engl. 2017;56(28):8231-8235doi: 10.1002/anie.201703789.
Guo, F., Yang, P., Pan, Z., Cao, X. N., Xie, Z., & Wang, X. (2017). Carbon-Doped BN Nanosheets for the Oxidative Dehydrogenation of Ethylbenzene. Angewandte Chemie (International ed. in English), 56(28), 8231-8235. https://doi.org/10.1002/anie.201703789
Guo, Fangsong, et al. "Carbon-Doped BN Nanosheets for the Oxidative Dehydrogenation of Ethylbenzene." Angewandte Chemie (International ed. in English) vol. 56,28 (2017): 8231-8235. doi: https://doi.org/10.1002/anie.201703789
Guo F, Yang P, Pan Z, Cao XN, Xie Z, Wang X. Carbon-Doped BN Nanosheets for the Oxidative Dehydrogenation of Ethylbenzene. Angew Chem Int Ed Engl. 2017 Jul 03;56(28):8231-8235. doi: 10.1002/anie.201703789. Epub 2017 Jun 12. PMID: 28514048.
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Angew Chem Int Ed Engl. 2017 Jul 03;56(28):8231-8235. doi: 10.1002/anie.201703789. Epub 2017 Jun 12.

Carbon-Doped BN Nanosheets for the Oxidative Dehydrogenation of Ethylbenzene.

Angewandte Chemie (International ed. in English)

Fangsong Guo, Pengju Yang, Zhiming Pan, Xu-Ning Cao, Zailai Xie, Xinchen Wang

Affiliations

  1. State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 3, 50002, China.

PMID: 28514048 DOI: 10.1002/anie.201703789

Abstract

Carbon-based catalysts have demonstrated great potential for the aerobic oxidative dehydrogenation reaction (ODH). However, its widespread application is retarded by the unavoidable deactivation owing to the appearance of coking or combustion under ODH conditions. The synthesis and characterization of porous structure of BCN nanosheets as well as their application as a novel catalyst for ODH is reported. Such BCN nanosheets consist of hybridized, randomly distributed domains of h-BN and C phases, where C, B, and N were confirmed to covalent bond in the graphene-like layers. Our studies reveal that BCN exhibits both high activity and selectivity in oxidative dehydrogenation of ethylbenzene to styrene, as well as excellent oxidation resistance. The discovery of such a simple chemical process to synthesize highly active BCN allows the possibility of carbocatalysis to be explored.

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: borocarbonitrides; carbocatalysis; microporous materials; oxidative dehydrogenation

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