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Inorg Chem. 2017 May 01;56(9):4966-4977. doi: 10.1021/acs.inorgchem.6b03163. Epub 2017 Apr 20.

Role of Mediator and Effects of Temperature on ortho-C-N Bond Fusion Reactions of Aniline Using Ruthenium Templates: Isolation and Characterization of New Ruthenium Complexes of the in-Situ-Generated Ligands.

Inorganic chemistry

Suman K Roy, Debabrata Sengupta, Santi Prasad Rath, Tanushri Saha, Subhas Samanta, Sreebrata Goswami

Affiliations

  1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science , Kolkata 700 032, India.
  2. Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur , Nadia 741246, India.

PMID: 28426213 DOI: 10.1021/acs.inorgchem.6b03163

Abstract

In this work, ortho-C-N bond fusion reactions of aniline are followed by the use of two different ruthenium mediators. Reaction of aniline with [Ru

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