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Inorg Chem. 2017 Jun 05;56(11):6225-6233. doi: 10.1021/acs.inorgchem.7b00282. Epub 2017 May 11.

Zero in-Plane Thermal Expansion in Guest-Tunable 2D Coordination Polymers.

Inorganic chemistry

Ryo Ohtani, Arnaud Grosjean, Ryuta Ishikawa, Riho Yamamoto, Masaaki Nakamura, Jack K Clegg, Shinya Hayami

Affiliations

  1. School of Chemistry and Molecular Biosciences, The University of Queensland , Brisbane St. Lucia, Queensland 4072, Australia.
  2. Department of Chemistry, Faculty of Science, Fukuoka University , 8-19-1 Nanakuma, Jonan-ku, Fukuoka 814-0180, Japan.

PMID: 28492319 DOI: 10.1021/acs.inorgchem.7b00282

Abstract

Zero in-plane thermal expansion (TE) in a two-dimensional (2D) coordination polymer is demonstrated. The combination of components that expand and those that shrink into zigzag layers results in no net area change in the 2D materials with temperature. Single crystals of [Mn(salen)]

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