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Taylor JW, McSkimming A, Moret ME, et al. A Molecular Boroauride: A Donor-Acceptor Complex of Anionic Gold. Angew Chem Int Ed Engl. 2017;56(35):10413-10417doi: 10.1002/anie.201703235.
Taylor, J. W., McSkimming, A., Moret, M. E., & Harman, W. H. (2017). A Molecular Boroauride: A Donor-Acceptor Complex of Anionic Gold. Angewandte Chemie (International ed. in English), 56(35), 10413-10417. https://doi.org/10.1002/anie.201703235
Taylor, Jordan W, et al. "A Molecular Boroauride: A Donor-Acceptor Complex of Anionic Gold." Angewandte Chemie (International ed. in English) vol. 56,35 (2017): 10413-10417. doi: https://doi.org/10.1002/anie.201703235
Taylor JW, McSkimming A, Moret ME, Harman WH. A Molecular Boroauride: A Donor-Acceptor Complex of Anionic Gold. Angew Chem Int Ed Engl. 2017 Aug 21;56(35):10413-10417. doi: 10.1002/anie.201703235. Epub 2017 Jun 27. PMID: 28589611.
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Angew Chem Int Ed Engl. 2017 Aug 21;56(35):10413-10417. doi: 10.1002/anie.201703235. Epub 2017 Jun 27.

A Molecular Boroauride: A Donor-Acceptor Complex of Anionic Gold.

Angewandte Chemie (International ed. in English)

Jordan W Taylor, Alex McSkimming, Marc-Etienne Moret, W Hill Harman

Affiliations

  1. Department of Chemistry, University of California-Riverside, Riverside, CA, 92521, USA.
  2. Organic Chemistry & Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands.

PMID: 28589611 DOI: 10.1002/anie.201703235

Abstract

Gold is unique among the transition metals in that it is stable as an isolated anion (auride). Despite this fact, the coordination chemistry of anionic gold is virtually nonexistent, and this unique oxidation state is not readily exploited in conventional solution chemistry owing to its high reactivity. Through the use of a new molecular scaffold based on diboraanthracene (B

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: boron; donor-acceptor systems; electrochemistry; gold; ligand design

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