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J Phys Chem Lett. 2017 Jul 06;8(13):2875-2880. doi: 10.1021/acs.jpclett.7b01003. Epub 2017 Jun 13.

Inhibiting Low-Frequency Vibrations Explains Exceptionally High Electron Mobility in 2,5-Difluoro-7,7,8,8-tetracyanoquinodimethane (F.

The journal of physical chemistry letters

Ivan Yu Chernyshov, Mikhail V Vener, Elizaveta V Feldman, Dmitry Yu Paraschuk, Andrey Yu Sosorev

Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences , Leninskii prosp. 31, Moscow 119991, Russia.
  2. G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences , Academicheskaya 1, 153045 Ivanovo, Russia.
  3. Faculty of Physics and International Laser Center, M.V. Lomonosov Moscow State University , Moscow 119991, Russia.

PMID: 28590744 DOI: 10.1021/acs.jpclett.7b01003

Abstract

Organic electronics requires materials with high charge mobility. Despite decades of intensive research, charge transport in high-mobility organic semiconductors has not been well understood. In this Letter, we address the physical mechanism underlying the exceptionally high band-like electron mobility in F

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