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Inorg Chem. 2017 Jun 05;56(11):6281-6296. doi: 10.1021/acs.inorgchem.7b00360. Epub 2017 May 22.

Spin Crossover in Double Salts Containing Six- and Four-Coordinate Cobalt(II) Ions.

Inorganic chemistry

Joanna Palion-Gazda, Barbara Machura, Rafal Kruszynski, Thais Grancha, Nicolás Moliner, Francesc Lloret, Miguel Julve

Affiliations

  1. Department of Crystallography, Institute of Chemistry, University of Silesia , Ninth Szkolna Street, 40006 Katowice, Poland.
  2. Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Lodz University of Technology , 116 ?eromski Street, 90-924 ?ód?, Poland.
  3. Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), Universitat de València , C/Catedrático José Beltrán 2, 46980 Paterna, València, Spain.

PMID: 28530402 DOI: 10.1021/acs.inorgchem.7b00360

Abstract

The preparation and spectroscopic and structural characterization of three cobalt(II) complexes of formulas [Co(tppz)

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