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Inorg Chem. 2017 Jul 17;56(14):8106-8113. doi: 10.1021/acs.inorgchem.7b00794. Epub 2017 Jun 28.

Probing Nuclear Spin Effects on Electronic Spin Coherence via EPR Measurements of Vanadium(IV) Complexes.

Inorganic chemistry

Michael J Graham, Matthew D Krzyaniak, Michael R Wasielewski, Danna E Freedman

Affiliations

  1. Department of Chemistry and ‡Argonne-Northwestern Solar Energy Research Center, Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208-3113, United States.

PMID: 28657714 DOI: 10.1021/acs.inorgchem.7b00794

Abstract

Quantum information processing (QIP) has the potential to transform numerous fields from cryptography, to finance, to the simulation of quantum systems. A promising implementation of QIP employs unpaired electronic spins as qubits, the fundamental units of information. Though molecular electronic spins offer many advantages, including chemical tunability and facile addressability, the development of design principles for the synthesis of complexes that exhibit long qubit superposition lifetimes (also known as coherence times, or T

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