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Chem Sci. 2017 May 01;8(5):3781-3788. doi: 10.1039/c6sc05268a. Epub 2017 Mar 13.

Superconductivity and magnetism in iron sulfides intercalated by metal hydroxides.

Chemical science

Xiuquan Zhou, Christopher Eckberg, Brandon Wilfong, Sz-Chian Liou, Hector K Vivanco, Johnpierre Paglione, Efrain E Rodriguez

Affiliations

  1. Department of Chemistry and Biochemistry , University of Maryland , College Park , MD 20742 , USA . Email: [email protected].
  2. Department of Physics , University of Maryland , College Park , MD 20742 , USA.
  3. Center for Nanophysics and Advanced Materials , University of Maryland , College Park , MD 20742 , USA.
  4. AIM Lab , Maryland NanoCenter , University of Maryland , College Park , MD 20742 , USA.

PMID: 28580110 PMCID: PMC5436553 DOI: 10.1039/c6sc05268a

Abstract

Inspired by naturally occurring sulfide minerals, we present a new family of iron-based superconductors. A metastable form of FeS known as the mineral mackinawite forms two-dimensional sheets that can be readily intercalated by various cationic guest species. Under hydrothermal conditions using alkali metal hydroxides, we prepare three different cation and metal hydroxide-intercalated FeS phases including (Li

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