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Qi X, Jiang LB, Zhou C, et al. Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions. ChemistryOpen. 2017;6(3):345-349doi: 10.1002/open.201700036.
Qi, X., Jiang, L. B., Zhou, C., Peng, J. B., & Wu, X. F. (2017). Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions. ChemistryOpen, 6(3), 345-349. https://doi.org/10.1002/open.201700036
Qi, Xinxin, et al. "Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions." ChemistryOpen vol. 6,3 (2017): 345-349. doi: https://doi.org/10.1002/open.201700036
Qi X, Jiang LB, Zhou C, Peng JB, Wu XF. Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions. ChemistryOpen. 2017 Mar 16;6(3):345-349. doi: 10.1002/open.201700036. eCollection 2017 Jun. PMID: 28638765; PMCID: PMC5474665.
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ChemistryOpen. 2017 Mar 16;6(3):345-349. doi: 10.1002/open.201700036. eCollection 2017 Jun.

Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions.

ChemistryOpen

Xinxin Qi, Li-Bing Jiang, Chao Zhou, Jin-Bao Peng, Xiao-Feng Wu

Affiliations

  1. Department of Chemistry Zhejiang Sci-Tech University Xiasha Campus Hangzhou 310018 P.R. China.
  2. Leibniz-Institut für Katalyse e.V. an der Universität Rostock Albert-Einstein-Straße 29a 18059 Rostock Germany.

PMID: 28638765 PMCID: PMC5474665 DOI: 10.1002/open.201700036

Abstract

A convenient and general zinc-catalyzed borylation of aryl diazonium salts and aryltriazenes has been developed. With bis- (pinacolato)diboron as the borylation reagent, aryldiazonium tetrafluoroborate salts and aryltriazenes were transformed into the corresponding arylboronates in moderate to excellent yields under mild conditions. As a convenient and practical methodology, no additional ligands, base, or any other additives are required here.

Keywords: arylboronates; aryldiazonium salts; aryltriazenes; borylation; zinc catalysis

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